Rate coefficients for the dissociative recombination, vibrational excitation and vibrational de-excitation of the BeT+ ion for all vibrational levels of its ground electronic state (X-1 Sigma(+), v(i)(+) = 0, …, 27) are reported, including in the calculation the contribution of super-excited states of the BeT complex pertaining to three electronic symmetries – (2)Pi, (2)Sigma(+), and (2)Delta. These data are suitable for the kinetic modeling of beryllium and tritium containing plasma, as encountered in magnetic fusion devices with beryllium walls (JET, ITER). In the present study we restrict ourselves to incident electron energies from 10(-3) up to 2.7 eV, and to electron temperatures between 100 and 5000 K, respectively. Together with our earlier and closely related studies on the BeH+ and BeD+ systems, this present work completes the isotopic coverage for the beryllium monohydride ions. The vibrational energy (rather than the vibrational quantum state) is identified as a proper isotopic similarity parameter, e.g., for reduced but still isotopically correct plasma chemistry models.
Reactive collisions between electrons and BeT+: Complete set of thermal rate coefficients up to 5000 K
Pop N.; Iacob F.; Niyonzima S.; Abdoulanziz A.; Laporta V.; Reiter D.; Schneider I.F.; Mezei J.Z.
Journal:
Atomic data and nuclear data tables (Print) 139 pp. 101414-1 - 101414-28
Year:
2021
ISTP Authors: Vincenzo Laporta
Keywords: plasma-wall interaction, Dissociative recombination, Beryllium monohydride, Vibrational excitation, Isotopic effect
Research Activitie: JOURNAL ARTICLES
Related products
-
PCCP. Physical chemistry chemical physics (Print) 23 (29), pp. 15475 - 15479 Year: 2021 DOI: 10.1039/d1cp01976g
Reconciling experimental and theoretical vibrational deactivation in low-energy O + N2 collisions
Hong, Q., Bartolomei, M., Esposito, F., Sun, Q., Pirani, F.
-
Chemical physics letters (Print) 773 pp. 138603-1 - 138603-6 Year: 2021 DOI: 10.1016/j.cplett.2021.138603
Dispersion energy effects on oxygen interaction with cesiated molybdenum surfaces
Sanna N.; Rutigliano M.; Palma A.
-
Acta astronautica 191 pp. 178 - 192 Year: 2021 DOI: 10.1016/j.actaastro.2021.10.040
Unsteady behavior and thermochemical non equilibrium effects in hypersonic double-wedge flows
Ninni D.; Bonelli F.; Colonna G.; Pascazio G.
English
Italiano