{"id":7522,"date":"2021-01-27T10:00:40","date_gmt":"2021-01-27T10:00:40","guid":{"rendered":"https:\/\/www.istp.cnr.it\/?post_type=product&#038;p=7522"},"modified":"2022-06-21T09:54:20","modified_gmt":"2022-06-21T09:54:20","slug":"kinetics-versus-thermodynamics-on-co2-dissociation-in-high-temperature-microwave-discharges","status":"publish","type":"product","link":"https:\/\/www.istp.cnr.it\/it\/research-product\/kinetics-versus-thermodynamics-on-co2-dissociation-in-high-temperature-microwave-discharges\/","title":{"rendered":"Kinetics versus thermodynamics on CO2 dissociation in high temperature microwave discharges"},"content":{"rendered":"<p>Recent experiments by Groen et al (2019 Plasma Sources Sci. Technol. 28 075016) on CO2 activation at high translational temperature (3500 T-g < 5500 K) are analyzed with a self-consistent code describing the vibrational kinetics of reacting CO2 together with CO and O-2 and the corresponding electron Boltzmann equation. The kinetics results are compared with the corresponding thermodynamics values. This comparison shows that the major components of the mixture, i.e. CO and O can be described by the thermodynamic approach, while the other minor components present large deviation from equilibrium. A qualitative agreement is found between experimental and theoretical values of electron density, E\/N and electron temperature in both diffuse and contracted regimes. The theoretical vibrational distributions as well as the corresponding electron energy distribution functions present non-equilibrium effects even at the considered high translational temperature.\n<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Pietanza, L. D.; Colonna, G.; Capitelli, M.<\/p>\n","protected":false},"featured_media":1294,"comment_status":"closed","ping_status":"open","template":"","meta":[],"product_cat":[574],"product_tag":[2729,2730,2731,2728],"class_list":["post-7522","product","type-product","status-publish","has-post-thumbnail","hentry","product_cat-journal-articles","product_tag-microwave-co2-dissociation","product_tag-co2-vibrational-kinetics","product_tag-self-consistent-kinetics","product_tag-co2","prodpage-style2"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product\/7522","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/comments?post=7522"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/media\/1294"}],"wp:attachment":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/media?parent=7522"}],"wp:term":[{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product_cat?post=7522"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product_tag?post=7522"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}