{"id":6650,"date":"2021-09-21T10:08:59","date_gmt":"2021-09-21T10:08:59","guid":{"rendered":"https:\/\/www.istp.cnr.it\/?post_type=product&#038;p=6650"},"modified":"2022-06-21T09:57:14","modified_gmt":"2022-06-21T09:57:14","slug":"complexes-of-the-noble-gas-atoms-with-unsaturated-ions-a-theoretical-investigation-on-the-exemplary-h2c-nh2-ar","status":"publish","type":"product","link":"https:\/\/www.istp.cnr.it\/it\/research-product\/complexes-of-the-noble-gas-atoms-with-unsaturated-ions-a-theoretical-investigation-on-the-exemplary-h2c-nh2-ar\/","title":{"rendered":"Complexes of the noble-gas atoms with unsaturated ions: A theoretical investigation on the exemplary (H2C = NH2 +)Ar"},"content":{"rendered":"<p>The (H2C = NH2<br \/>\n+)Ar isomeric complexes recently observed by Duncan and coworkers using gas phase infrared<br \/>\nspectroscopy [Chem. Phys. Lett. 726 (2019) 53-56] were theoretically investigated by different techniques of<br \/>\nbonding analysis. The higher stability of the NH-coordinated complex with respect to the C-coordinated one<br \/>\narises from a major contribution of the inductive binding component, the electrostatic and dispersion contributions<br \/>\nbeing, instead, comparable in the two isomers. A similar situation expectedly occurs in other complexes<br \/>\nof the noble-gas atoms with unsaturated and aromatic ions, observed to feature the competitive occurrence<br \/>\nof a more stable H-bonded isomer and a less stable ?-stacked one.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Borocci S.; Grandinetti F.; Sanna N.<\/p>\n","protected":false},"featured_media":1294,"comment_status":"closed","ping_status":"open","template":"","meta":[],"product_cat":[574],"product_tag":[1039,1040,1041,1042,1043],"class_list":["post-6650","product","type-product","status-publish","has-post-thumbnail","hentry","product_cat-journal-articles","product_tag-bonding-analysis","product_tag-electron-energy-density","product_tag-nci-analysis","product_tag-noble-gas-non-covalent-complexes","product_tag-sapt-calculations","prodpage-style2"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product\/6650","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/comments?post=6650"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/media\/1294"}],"wp:attachment":[{"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/media?parent=6650"}],"wp:term":[{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product_cat?post=6650"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/www.istp.cnr.it\/it\/wp-json\/wp\/v2\/product_tag?post=6650"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}